2-Butyl-5-pentylbenzene-1,3-diol
نویسندگان
چکیده
In the title compound, C(15)H(24)O(2), a natural dialkyl-resorcinol commonly named stemphol, the mol-ecules are linked into C(6) and C(2) (2)(4) chains and R(4) (4)(16) rings by inter-molecular O-H⋯O hydrogen bonds, creating mol-ecular sheets parallel to the (010) plane. The alkyl chains are directed orthogonally away from these planes in almost complete extension.
منابع مشابه
Diastereoselective synthesis of pitavastatin calcium via bismuth-catalyzed two-component hemiacetal/oxa-Michael addition reaction.
An efficient and concise asymmetric synthesis of pitavastatin calcium (1) starting from commercially available (S)-epichlorohydrin is described. A convergent C1 + C6 route allowed for the assembly of the pitavastatin C7 side chain via a Wittig reaction between phosphonium salt 2 and the enantiomerically pure C6-formyl side chain 3. The 1,3-syn-diol acetal motif in 3 was established with excelle...
متن کاملIntroduction of ester and amido functions in tetrairon(III) single-molecule magnets: synthesis and physical characterization.
Tetrairon(III) complexes with a propeller-like structure derived from [Fe(4)(OMe)(6)(dpm)(6)] (1) (Hdpm = 2,2,6,6-tetramethylheptane-3,5-dione) are providing a growing class of Single Molecule Magnets (SMMs) displaying unprecedented synthetic flexibility and ease of functionalization. Herein we report the synthesis, crystal structures and magnetic properties of two novel tetrairon(III) SMMs, [F...
متن کاملSynthesis and structure of the mercury chloride complex of 2,2′-(2-bromo-5-tert-butyl-1,3-phenylene)bis(1-methyl-1H-benzimidazole)
In the title mercury complex, catena-poly[[di-chlorido-mercury(II)]-μ-2,2'-(2-bromo-5-tert-butyl-1,3-phenyl-ene)bis-(1-methyl-1H-benzimidazole)-κ2N3:N3'], [HgCl2(C26H25BrN4)] n , the HgII atom is coordinated by two Cl atoms and by two N atoms from two 2,2'-(2-bromo-5-tert-butyl-1,3-phenyl-ene)bis-(1-methyl-1H-benzimidazole) ligands. The metal cation adopts a distorted tetrahedral coordination g...
متن کامل5-tert-Butyl-2-[5-(5-tert-butyl-1,3-benzoxazol-2-yl)-2-thienyl]-1,3-benzoxazole
The title compound, C(26)H(26)N(2)O(2)S, was prepared by the reaction of thio-phene-2,5-dicarboxylic acid and 2-amino-4-tert-butyl-phenol. One of the tert-butyl groups is disordered over two conformations, with occupancies of 0.539 (1) and 0.461 (2). The two 1,3-benzoxazole rings are almost planar, with dihedral angles of 0.83 (18) and 1.64 (17)° between the five- and six-membered rings. The th...
متن کامل2-[(5-Chloro-2-oxidobenzylidene)azaniumyl]-2-methylpropane-1,3-diol
The title compound, C(11)H(14)ClNO(3), was prepared by the condensation of equimolar quanti-ties of 5-chloro-salicyl-aldehyde and 2-amino-2-methyl-propane-1,3-diol in methanol. In the crystal, it exists in the zwitterionic form, with nominal proton transfer from the phenol group to the imine N atom. This results in the formation of an intra-molecular N-H⋯O hydrogen bond, which generates an S(6)...
متن کامل